Coordination of {Mo142} Ring to La3+ Provides Elliptical {Mo134La10} Ring with a Variety of Coordination Modes
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منابع مشابه
Coordination of {Mo142} Ring to La3+ Provides Elliptical {Mo134La10} Ring with a Variety of Coordination Modes
A 28-electron reduced C2h-Mo-blue 34Ǻ outer ring diameter circular ring, [Mo142O429H10(H2O)49(CH3CO2)5(C2H5CO2)] (≡{Mo142(CH3CO2)5(C2H5CO2)}) comprising eight carboxylate-coordinated (with disorder) {Mo2} linkers and six defect pockets in two inner rings (four and three for each, respectively), reacts with La in aqueous solutions at pH 3.5 to yield a 28-electron reduced elliptical Ci-Mo-blue ri...
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ژورنال
عنوان ژورنال: Materials
سال: 2009
ISSN: 1996-1944
DOI: 10.3390/ma3010064